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51.
52.
Flame-retardant plastics, such as desktop and laptop personal computer bodies, could be completely liquefied by carbon materials-catalyzed
hydroliquefaction in tetralin without using H2 as a hydrogen source. Active carbons with larger surface areas (1450–3450 m2/g) acted as superior catalysts in transferring tetralin hydrogens to plastics. On the other hand, carbon blacks and fullerene-rich
soot were less active catalysts. Graphite and mesocarbon microbeads did not show any catalytic effects. Benzene, toluene,
and ethylbenzene were obtained as recyclable hydrocarbons; their total amounts varied from 4 wt% to 12 wt% depending on the
types of plastics and the carbon materials used. Organic bromides such as polybromodioxins were not contained in the gases
and oils of the product.
Received: July 19, 2000 / Accepted: September 17, 2000 相似文献
53.
Pyrolysis for the simultaneous generation of oils and gases can be convenient to obtain hydrocarbons and even to recover crude petrochemicals or to generate energy from waste plastics. A Gray–King apparatus has been used to pyrolyze waste polyethylene (PE), polystyrene (PS), both separately and with different compositions. Thermogravimetric analysis of waste plastics indicated the critical temperatures, which should be effective for pyrolysis. The chosen heating rate was low in order to achieve higher liquid yields. The results showed that waste PS yielded higher liquid, and waste PE yielded higher gaseous products. The dominant liquid product of PS waste was styrene whereas for waste PE, prophenylbenzene was the dominant pyrolysis product. 相似文献
54.
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56.
Christopher?H.?SchillingEmail author Piotr?Tomasik David?S.?Karpovich Bruce?Hart Sally?Shepardson Jagdeep?Garcha Paul?T.?Boettcher 《Journal of Polymers and the Environment》2004,12(4):257-264
Distillers dry grain (DDG) was derivatized either by carboxymethylation, glutaration, maleiation, phthallation, or succination in order to produce anionic materials suitable for complexation with soy protein isolate. Infrared spectroscopy confirmed that derivatization of DDG by all reagents was successful. Blending of derivatized anionic products with soy protein resulted in instant precipitation of gels. The gels were centrifuged, molded, and dried into solid pellets with tensile strengths as high as 1.67MPa, suggesting that these materials could be promising as biodegradable structural materials. Infrared spectroscopy suggested the possibility of complexes forming between soy protein isolate and each of the derivatized DDG samples. 相似文献
57.
可降解塑料生物降解性测试方法研究 总被引:2,自引:0,他引:2
通过对3种可陈解塑料生物降解性测试方法进行的实验研究,分析了各种方法的优缺点,对将来开发合理可行的标准测试方法提出了建议。 相似文献
58.
废旧塑料综合利用技术的应用 总被引:2,自引:0,他引:2
废旧塑料的回收利用是环境污染控制所面临的一个重要课题,近年来,人们在这方面进行了大量的研究工作,取得了很多成果.详细叙述了国内外废旧塑料回收处理的方法,分析了我国在废旧塑料回收利用方面的现状及存在的问题,并对如何进一步开展废旧塑料回收利用工作提出了一系列切实可行的建议. 相似文献
59.
废塑料的回收利用及降解塑料的生产现状 总被引:5,自引:0,他引:5
介绍了废塑料的再生利用,热分解回收低分子化合物和焚烧回收热能的技术,并对国内降解塑料的生产现状进行了评述。 相似文献
60.
废塑料在炼铁工艺中的应用 总被引:1,自引:0,他引:1
介绍了废塑料的处理和利用方法 ,叙述了高炉喷吹废塑料的工艺、优点和国外的实际应用。通过比较 ,认为在高炉中应用废塑料作还原剂能带来较好的社会效益和经济效益 ,指出随着喷吹技术的不断完善 ,高炉喷吹废塑料在我国具有广阔的应用前景 相似文献